Dr Mathe takes over from the interim CEO Lethabo Manamela who has held the position since March 2020.
The call to remove Mr Mashatile was made at Tuesday’s NEC meeting but was stifled because it was not on the agenda.
Erik ten Hag secured his first win as Manchester United manager with a 2-1 victory over Liverpool at Old Trafford.
Thomas Tuchel and Antonio Conte were both shown red cards following their angry altercation at full-time at Stamford Bridge.
The Red Devils are looking to secure a number of quality additions in the final fortnight of the transfer market.
Meanwhile Usuthu were unchanged from their win over Cape Town City on Saturday.
Newcastle were able to come to an agreement with Lyon over a mid-season move.
Casemiro was named on the bench for Real Madrid’s La Liga opener with Almeria last weekend.
Mabuza has revealed that municipalities’ debt in the country to power utility Eskom has increased to R49.1 billion.
Zuma-Sambudla posted a photo of herself earlier this week on social media.